化學反應方程式列表/鎝
這個列表記載了關於鎝的化學反應方程式。
- Tc + 2 Cl2 → TcCl4 在300–500 °C反應。[1]
- 4 Tc + 7 O2 → 2 Tc2O7 在450–500 °C反應。[2]
- Tc + 3 F2 → TcF6 氟氣過量，400 °C反應。[3]
- Tc2O7 + 7 CCl4 → 2 TcCl4 + 7 COCl2 + 3 Cl2
- Tc2O7 + 2 NaOH → 2 NaTcO4 + H2O
- TcCl4 + 2 HCl → H2TcCl6 得到黃色溶液
- TcBr4 + 2 PPh3 → TcBr4(PPh3)2 生成亮橙紅色的固體
- 2 NH4TcO4 → 2 TcO2 + 4 H2O + N2 700 °C分解
- ↑ Johnstone, Erik V.; Poineau, Frederic; Forster, Paul M.; Ma, Longzou; Hartmann, Thomas; Cornelius, Andrew; Antonio, Daniel; Sattelberger, Alfred P.; Czerwinski, Kenneth R. Technetium Tetrachloride Revisited: A Precursor to Lower-Valent Binary Technetium Chlorides. Inorganic Chemistry. 2012-07-09, 51 (15): 8462–8467. PMID 22775538. doi:10.1021/ic301011c （英語）.
- ↑ Herrell, A. Y.; Busey, R. H.; Gayer, K. H. Technetium(VII) Oxide, in Inorganic Syntheses XVII. 1977: 155–158. ISBN 0-07-044327-0.
- ↑ Selig, H.; Chernick, C.L.; Malm, J.G. The Preparation and Properties of TcF6. Journal of Inorganic and Nuclear Chemistry. 1961, 19 (3–4): 377–381. doi:10.1016/0022-1902(61)80132-2.