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钕化合物列表

来自维基学院

本列表收录钕元素的化合物,包含已有文献记载的化合物与原创研究。

格式:[化学式],[颜色],mp.[熔点,°C],bp.[沸点,°C],(dec)/dec.[分解温度],subl.[升华温度],d[温度,°C].[密度,g·cm−3],{结构},[溶解性],[化学活性(仅限于常见物质,如空气、水)、毒性],[参考文献]

  • NdF3,mp.1374,{六方},[W]
  • NdOF,{斜方}/{立方},[W]
  • NdCl2,暗绿色固体,mp.841,{PbCl2},[W]
  • NdCl3,mp.760,{UCl3},[W], [T]
  • NdBr2,{PbCl2},[T]
  • NdBr3,mp.684,{PuBr3},[W], [T]
  • NdI2,深紫色固体,mp.562,{SrBr2},[W]
  • NdI3,mp.775,{斜方},[W]
  • Nd2O3,浅蓝灰色,mp.2310,[W]
  • Nd(OH)3,玫瑰红色固体,难溶于水,[W]
  • Nd2O(OH)2(OOH)2,紫丁香色,[W]
  • Nd(NCS)3·4(C6H5)3PO,浅紫色晶体,mp.228-230,dec.250,d.1.370,{P21/c},[1]
  • NdSe,金色,[G3]
  • Nd3Se4,蓝黑色(带金属光泽),[G3]
  • Nd2Se3,红色或紫色,mp.1557,d.6.69,{Th3P4},在潮湿空气中分解,[G3]
  • Nd4Se7,d.6.54,[G3]
  • NdSe2,银灰色,d.6.88,[G3]
  • Nd2O2Se,蓝灰色,d.6.92,[G3]
  • NdH(SeO3)2·1.5H2O,紫丁香色晶体,遇水分解,[G3]
  • Nd2(SeO4)3·5H2O,粉色,[G3]
  • NdSeF,d.7.06,{四方,PbFCl},[G3]
  • Nd2SeF4,紫色,d.6.12,[G3]
  • NdTe,紫色,d.7.40,{NaCl},[G2]
  • Nd3Te4,黑灰色,[G2]
  • Nd2Te3,银灰色,d.7.10,{Th3P4;U2S3},[G2]
  • Nd4Te7,浅灰色,[G2]
  • NdTe2,灰色,[G2]
  • Nd2Te5,金色,[G2]
  • NdTe3,金色,[G2]
  • Nd2O2Te,暗绿色,d.7.18,[G2]
  • NdTeF,d.5.63,{PbFCl},[G2]
  • NdTe2O7F,{单斜},[G2]
  • Nd2TeO5,蓝色,[G2]
  • Nd2(TeO3)3,浅紫色,[G2]
  • Nd2Te4O11,d.6.30,[G2]
  • Nd2TeO6,d.6.72,蓝色,[G2]
  • Nd2(CO3)3·8H2O,[W]
  • Nd2(C2O4)3(H2O)6·nH2O,淡紫色晶体,[2]
  • Nd2(SO4)3·8H2O,红色,{单斜},[W]
  • Ba2CeNdO6,黑色,[W]
  • Nd(C5H5)3,淡红色至蓝色,mp.380,subl.220(10−3~10−4 mmHg),[W]
  • Nd(CH3C5H4)3,蓝紫色,[W]
  • Nd(OiPr)3[T]
  • Li3Nd3Te2O12,浅蓝色,[G2]
  • NdB4,金色晶体,[G1]
  • NdB6,蓝色(带紫色光泽),d.4.943,[G1]
  • Nd2(MoO4)3,蓝色[3]
  • Nd[Ag(CN)2]3,紫色晶体,d21.3.107,{P63/mcm}[4]
  • Nd[Au(CN)2]3,紫色晶体,d21.4.440,{P63/mcm}[4]

参考文献

[编辑 | 编辑源代码]
  1. 黄春辉, 徐荣芳, 徐小杰, 徐光宪. 中性磷(膦)类希土萃合物的结构研究——Ⅱ.四(三苯基氧膦)合硫氰酸钕的合成及结构测定. 无机化学学报, 1985 (1):106-115.
  2. Tamain, C.; Arab-Chapelet, B.; Rivenet, M.; Legoff, X. F.; Loubert, G.; Grandjean, S.; Abraham, F. Coordination Modes of Americium in the Am2(C2O4)3(H2O)6·4H2O Oxalate: Synthesis, Crystal Structure, Spectroscopic Characterizations and Comparison in the M2(C2O4)3(H2O)6·nH2O (M = Ln, An) Series. Inorganic Chemistry. 2015, 55 (1): 51–61. ISSN 0020-1669. doi:10.1021/acs.inorgchem.5b01781. 
  3. HUANG, Q; XU, J; LI, W. Preparation of tetragonal defect scheelite-type RE2(MoO4)3 (RE=La to Ho) by precipitation method. Solid State Ionics (Elsevier BV). 1989, 32–33: 244–249. ISSN 0167-2738. doi:10.1016/0167-2738(89)90228-2. 
  4. 4.0 4.1 Assefa, Zerihun; Kalachnikova, Katrina; Haire, Richard G.; Sykora, Richard E. Hydrothermal synthesis, structural, Raman, and luminescence studies of Am[M(CN)2]3·3H2O and Nd[M(CN)2]3·3H2O (M=Ag, Au): Bimetallic coordination polymers containing both trans-plutonium and transition metal elements. Journal of Solid State Chemistry (Elsevier BV). 2007, 180 (11): 3121–3129. ISSN 0022-4596. doi:10.1016/j.jssc.2007.08.032. 

字母注释

[编辑 | 编辑源代码]

  • E:实验
  • G1:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C11a Compounds with Boron. Springer-Verlag Berlin Heidelberg GmbH 1990. doi:10.1007/978-3-662-07503-6.
  • G2:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C10 Compounds with Te, Po. Springer-Verlag Berlin Heidelberg GmbH 1987.doi:10.1007/978-3-662-06366-8.
  • G3:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C9 Compounds with Se. Springer-Verlag Berlin Heidelberg GmbH 1986.doi:10.1007/978-3-662-06345-3.
  • T:Simon Cotton. Lanthanide and Actinide Chemistry - Inorganic Chemistry - A WILEY TEXTBOOK SERIES. John Wiley & Sons Ltd, 2006. ISBN: 9-78-0-470-01006-8.
  • W:无机化学丛书. 第七卷. 钪 稀土元素. 科学出版社