釤化合物列表
本列表收錄釤元素的化合物,包含已有文獻記載的化合物與原創研究。
格式:[化學式],[顏色],mp.[熔點,°C],bp.[沸點,°C],(dec)/dec.[分解溫度],subl.[升華溫度],d[溫度,°C].[密度,g·cm−3],{結構},[溶解性],[化學活性(僅限於常見物質,如空氣、水)、毒性],[參考文獻]
- SmF2,紫紅色固體,{螢石},[W]
- SmF3,mp.1306,bp.2327,{六方},[W]
- SmOF,{斜方}/{立方},[W]
- SmCl2,紅棕色固體,mp.855,{PbCl2},[W]
- SmCl3,mp.678,{六方},[W]
- SmBr2,紅棕色固體,mp.669,{SrBr2}/{PbCl2},[W]
- SmBr3,mp.664,bp.1645,{PuBr3},[T],[W]
- SmI2,深綠色固體,mp.520,{EuI2},[W]
- SmI3,mp.820,{六方}
- SmBrI2,[1]
- SmClI2,[1]
- SmO,紅色,[W]
- Sm2O3,乳黃色,mp.2320,[W]
- Sm(OH)2,綠色固體,[W]
- Sm(OH)3,黃色固體,難溶於水,[W]
- Sm2O(OH)2(OOH)2,奶油黃色,[W]
- SmSe,灰黑色,[G3]
- Sm3Se4,藍黑色(帶金屬光澤),[G3]
- Sm2Se3,黑色或灰黑色,d.7.02,{Th3P4},在潮濕空氣中分解,[G3]
- Sm4Se7,d.6.80,[G3]
- SmSe1.8,d.6.98,[G3]
- SmSe2,銀灰色,d.7.20,[G3]
- Sm2O2Se,灰色或暗紅色,d.7.39,[G3]
- Sm2(SeO4)3·7H2O,白色,[G3]
- Sm2(SeO4)3·8H2O,d.3.32,[G3]
- SmTe,黑灰色,mp.1860±50,{低壓:NaCl;高壓:CsCl},遇空氣分解,[G2]
- Sm3Te4,黑色,[G2]
- Sm4Te7,深灰色,[G2]
- SmTe1.85,淺灰色,[G2]
- Sm2Te5,棕色,[G2]
- SmTe3,棕色(金色光澤),[G2]
- Sm2O2Te,髒綠色,d.7.58,[G2]
- Sm2TeO5,奶黃色,[G2]
- Sm2(TeO3)3,淺黃色,[G2]
- Sm2Te4O11,d.6.48,[G2]
- Sm2TeO6,d.7.04,奶黃色,[G2]
- SmSO4,橘黃色固體,[W]
- SmPo,d.7.87,{NaCl},[G2]
- SmCO3,橙棕色固體,[W]
- Sm2(CO3)3·3H2O,[W]
- Sm2(SO4)3·8H2O,黃色,{單斜},[W]
- Sm(CH3COO)3·4H2O,{三斜},[W]
- Sm(C5H5)3,橙色,mp.365,subl.220(10−3~10−4 mmHg),[W]
- (C5H5)2SmCl,黃色,dec.200,[W]
- Sm(C9H7)3(OC4H8) ,深紅色,[W]
- (Ph3PH)3SmI6,[T]
- Li3Sm3Te2O12,淺黃色,[G2]
- SmB4,藍色晶體,{UB4},[G1]
- SmB6,藍色,d.5.071,[G1]
- SmB66,{YB66},[G1]
- ↑ 1.0 1.1 Nomura, Ryoji; Matsuno, Tatsuya; Endo, Takeshi. Samarium Iodide-Catalyzed Pinacol Coupling of Carbonyl Compounds. Journal of the American Chemical Society. 1996, 118 (46): 11666–11667. ISSN 0002-7863. doi:10.1021/ja962331a.
- E:實驗
- G1:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C11a Compounds with Boron. Springer-Verlag Berlin Heidelberg GmbH 1990. doi:10.1007/978-3-662-07503-6.
- G2:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C10 Compounds with Te, Po. Springer-Verlag Berlin Heidelberg GmbH 1987.doi:10.1007/978-3-662-06366-8.
- G3:Gmelin Handbook of Inorganic Chemistry - 8th Edition. Sc, Y, La-Lu RARE EARTH ELEMENTS. C9 Compounds with Se. Springer-Verlag Berlin Heidelberg GmbH 1986.doi:10.1007/978-3-662-06345-3.
- T:Simon Cotton. Lanthanide and Actinide Chemistry - Inorganic Chemistry - A WILEY TEXTBOOK SERIES. John Wiley & Sons Ltd, 2006. ISBN: 9-78-0-470-01006-8.
- W:無機化學叢書. 第七卷. 鈧 稀土元素. 科學出版社
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